Molecular catalysis

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CiteScore values are based on citation counts in a range of four years e. Impact Factor: 3. This free service is available to anyone who has published and whose publication is in Scopus. Researcher Academy Author Resources Try out personalized alert features. Molecular Catalysis - Editorial Board.

Rafael Luque. Jeong Woo Han. Frank Hollmann. In Kyu Song. Giovanni Talarico. Takashi Tatsumi. Ning Yan, PhD. Ariga, PhD.

molecular catalysis

Gong, PhD. S Lutz. M Rueping. Molecular Catalysis. Librarians Order Journal.Once production of your article has started, you can track the status of your article via Track Your Accepted Article.

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From JanuaryProf. Luque was appointed Editor-in-chief of Molecular Catalysis Elsevier. To send an email to Rafael Luque please complete the short form below. Please note that all enquiries should relate specifically to Molecular Catalysis.

All the fields are required so please make sure you complete them all otherwise we won't be able to send your message. Submit Your Paper. Supports Open Access. View Articles. Track Your Paper Check submitted paper Check the status of your submitted manuscript in the submission system Track accepted paper Once production of your article has started, you can track the status of your article via Track Your Accepted Article. Order Journal. Journal Metrics CiteScore : 7.

CiteScore values are based on citation counts in a range of four years e. Impact Factor: 3. This free service is available to anyone who has published and whose publication is in Scopus. Researcher Academy Author Resources Try out personalized alert features. Rafael Luque. Molecular Catalysis. Librarians Order Journal.These metrics are regularly updated to reflect usage leading up to the last few days.

molecular catalysis

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online.

Clicking on the donut icon will load a page at altmetric. Find more information on the Altmetric Attention Score and how the score is calculated. Metal—organic frameworks MOFs are appealing heterogeneous support matrices that can stabilize molecular catalysts for the electrochemical conversion of small molecules. However, moving from a homogeneous environment to a porous film necessitates the transport of both charge and substrate to the catalytic sites in an efficient manner.

This presents a significant challenge in the application of such materials at scale, since these two transport phenomena charge and mass transport would need to operate faster than the intrinsic catalytic rate in order for the system to function efficiently.

Thus, understanding the fundamental kinetics of MOF-based molecular catalysis of electrochemical reactions is of crucial importance. In this Perspective, we quantitatively dissect the interplay between the two transport phenomena and the catalytic reaction rate by applying models from closely related fields to MOF-based catalysis.

The identification of the limiting process provides opportunities for optimization that are uniquely suited to MOFs due to their tunable molecular structure. This will help guide the rational design of efficient and high-performing catalytic MOF films with incorporated molecular catalyst for electrochemical energy conversion. A full list of all dimensional symbols and their definitions is given in the Symbols section. Figure 1. Dimensionless concentration is displayed on the y -axis, where C S is the substrate concentration inside the MOF particle a function of the radial distance rand C S 0 is the bulk substrate concentration taken as constant outside the particle for simplicity.

The dimensionless radial coordinate R a is the particle radius is plotted on the x -axis. Figure 2. Figure 3. Current i is normalized to the semi-infinite current. Current—potential responses were generated numerically with finite difference method.

Figure 4. Figure 5.This is a short guide how to format citations and the bibliography in a manuscript for Journal of Molecular Catalysis. A, Chemical. For a complete guide how to prepare your manuscript refer to the journal's instructions to authors.

Typically you don't format your citations and bibliography by hand. The easiest way is to use a reference manager:. Those examples are references to articles in scholarly journals and how they are supposed to appear in your bibliography. Not all journals organize their published articles in volumes and issues, so these fields are optional.

Molecular Catalysis - Editorial Board

Some electronic journals do not provide a page range, but instead list an article identifier. In a case like this it's safe to use the article identifier instead of the page range. Sometimes references to web sites should appear directly in the text rather than in the bibliography.

Refer to the Instructions to authors for Journal of Molecular Catalysis. This example shows the general structure used for government reports, technical reports, and scientific reports. If you can't locate the report number then it might be better to cite the report as a book.

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For reports it is usually not individual people that are credited as authors, but a governmental department or agency like "U. Theses including Ph. Unlike scholarly journals, news papers do not usually have a volume and issue number. Instead, the full date and page number is required for a correct reference.

Guides Resources Citation styles. How to format your references using the Journal of Molecular Catalysis. A, Chemical citation style This is a short guide how to format citations and the bibliography in a manuscript for Journal of Molecular Catalysis. Using reference management software Typically you don't format your citations and bibliography by hand.

EndNote Find the style here: output styles overview Mendeley, Zotero, Papersand others The style is either built in or you can download a CSL file that is supported by most references management programs. Check the instructions to authors if the publisher offers a LaTeX template for this journal. Journal articles Those examples are references to articles in scholarly journals and how they are supposed to appear in your bibliography.

A journal article with 1 author. Saper, Biomedicine. Life, the universe, and body temperature, Science. A journal article with 2 authors. Xu, M. Norell, A new troodontid dinosaur from China with avian-like sleeping posture, Nature.

A journal article with 3 authors. Schneider, J. Kelly, Trans-suppression of misfolding in an amyloid disease, Science. A journal article with 4 or more authors. Brashares, P.Journal of Molecular Catalysis A: Chemical publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms in homogeneous catalysisheterogeneous catalysis including supported organometallic catalysis Journal of Molecular Catalysis A: Chemical publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms in homogeneous catalysisheterogeneous catalysis including supported organometallic catalysis and computational catalysis.

The Journal also publishes timely reviews of specialized topics within the scope outlined above, however prospective authors must obtain preliminary approval from the Editor-in-Chief before preparing such an article. Accepted manuscripts of exceptional quality and substantial interest to the readership may be selected by Editors to feature in the 'Editors Choice' section of the Journal. Contributions that do not fall within the above aims and scope will be rejected at the editorial level.

Examples of papers falling into this category are those for which the major focus is on preparative inorganic chemistry and associated structural characterisation, on polymer characterisation, or on the synthetic organic applications of catalysis, rather than the molecular and atomic aspects of catalytic activation and reaction mechanism. In keeping with the aims and scope of the journal, it is expected that catalyst activity be appropriately expressed. Thus, homogeneous systems are ideally characterised by kinetic analysis from which macro- or micro-scopic rate constants can be presented.

At the very minimum, turnover number and frequency should be reported.

molecular catalysis

For heterogeneous catalysis, activity should ideally be expressed in turnover frequencies per site or at least per unit area of active component measured using an appropriate method, such as chemisorption or estimated from the particle size obtained by such techniques as transmission electron microscopy or XRD line-broadening.

Extensive use of percent conversion should be avoided. ISSN: Journal of Molecular Catalysis A: Chemical. View Articles. Your Research Data Share your research data. This free service is available to anyone who has published and whose publication is in Scopus. Researcher Academy Author Resources Try out personalized alert features.

Continued as Molecular Catalysis. Read more. Jean Marcel R. Gallo Roberto Rinaldi. Atsushi Fukuoka Dmitry Murzin Alexander Kirillov Dalmo Mandelli. Reviewers Reviewer Recognition Support Center.Earth-abundant Fe, Ni, and Co aza macrocyclic and polypyridine complexes have been thoroughly investigated for CO 2 electrochemical and visible-light-driven reduction.

Since the first reports in the s, an enormous body of work has been accumulated regarding the two-electron two-proton reduction of the gas, along with mechanistic and spectroscopic efforts to rationalize the reactivity and establish guidelines for structure—reactivity relationships.

The ability to fine tune the ligand structure and the almost unlimited possibilities of designing new complexes have led to highly selective and efficient catalysts. Recent efforts toward developing hybrid systems upon combining molecular catalysts with conductive or semi-conductive materials have converged to high catalytic performances in water solutions, to the inclusion of these catalysts into CO 2 electrolyzers and photo-electrochemical devices, and to the discovery of catalytic pathways beyond two electrons.

Combined with the continuous mechanistic efforts and new developments for in situ and in operando spectroscopic studies, molecular catalysis of CO 2 reduction remains a highly creative approach. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

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Issue 16, Previous Article Next Article. From the journal: Chemical Society Reviews. Molecular catalysis of CO 2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes.

Rafael Luque

This article is part of the themed collection: Earth Abundant Metals in Catalysis. This article is Open Access. Please wait while we load your content Something went wrong. Try again? Cited by.

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The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.

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Find more information on the Altmetric Attention Score and how the score is calculated. Molecular catalysis of H 2 production from the electrochemical reduction of acids by transition-metal complexes is one of the key issues of modern energy challenges. The question of whether it proceeds heterolytically through reaction of an initially formed metal hydride with the acid or homolytically through symmetrical coupling of two molecules of hydride has to date received inconclusive answers for a quite simple reason: the theoretical bases for criteria allowing the distinction between homolytic and heterolytic pathways in nondestructive methods such as cyclic voltammetry have been lacking heretofore.

They are provided here, allowing the distinction between the two pathways. The theoretical predictions and the diagnosing strategy are illustrated by catalysis of the reduction of phenol, acetic acid, and protonated triethylamine by electrogenerated iron 0 tetraphenylporphyrin. Rather than being an intrinsic property of the catalytic system, the occurrence of either a heterolytic or a homolytic pathway results from their competition as a function of the concentrations of acid and catalyst and the rate constants for hydride formation and H 2 evolution by hydride protonation or dimerization.

Experimental details and derivations of the equations allowing the establishment of the kinetic zone diagram and the various expressions and working curves depicting the variations of the plateau current and half-wave potential with the appropriate parameters. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only.

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Article Views Altmetric. Citations Supporting Information. Cited By. This article is cited by 59 publications. Jose L. Alvarez-Hernandez, Andrew E. Sopchak, Kara L.

Inorganic Chemistry59 12 Frontier, Angela Lombardi, Kara L. Biochemistry59 12 Margarit, Naomi G. Asimow, Cyrille Costentin, Daniel G. ACS Energy Letters5 1


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